Transmittance and Absorbance

When light passes through or is reflected from a sample, the amount of light absorbed is the difference between the incident radiation (\(I_0\)) and the transmitted radiation (\(I\)). The amount of light absorbed is expressed as absorbance.

Transmittance, or light that passes through a sample, is usually given in terms of a fraction of 1 or as a percentage and is defined as follows:

\[ T = \frac{I}{I_0} \]
or
\[ \%T = \frac{I}{I_0} \times 100 \]

Absorbance is defined as follows:

\[ A = -\log T \]

For most applications, absorbance values are used since the relationship between absorbance and both concentration and path length is normally linear as per the Beer-Lambert law.

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