What is the Photovoltaic Effect?
The photovoltaic effect is the process by which a material generates a voltage and electric current when exposed to light. This is the fundamental principle behind solar cells and solar panels, enabling direct conversion of light energy into electrical energy. The effect occurs most notably in semiconductor materials, particularly at a p-n junction, where light excites electrons, causing them to move and create electricity within the material itself.
How Does the Photovoltaic Effect Work?
- Photon Absorption: Light (photons) strikes a semiconductor (such as silicon) in a solar cell.
- Electron Excitation: Photons transfer energy to electrons, exciting them from the valence band to the conduction band, forming electron-hole pairs.
- Charge Separation: The internal electric field at the p-n junction causes electrons and holes to move in opposite directions.
- Generation of Electricity: Movement of electrons and holes creates a voltage and electric current that can be harnessed for external use.

Features
- Occurs in semiconductor materials with appropriate band gaps (typically 1.0 – 1.6 eV, like silicon)
- Depends on the absorption of photons with sufficient energy to excite electrons
- Crucial role played by p-n junction, which is formed by joining p-type and n-type materials
- Generates direct current (DC) electricity efficiently from sunlight.
Applications of the Photovoltaic Effect
- Solar Panels & Power Plants: Used for large-scale electricity generation, powering homes, industries, and grids.
- Portable Solar Devices: Solar chargers, lanterns, and calculators.
- Remote and Emergency Applications: PV cells power traffic signs, emergency phones, parking meters, and radio transmitters in remote locations.
- Spacecraft and Satellites: Provide reliable power sources for long missions.
- Water Pumps and Irrigation: Solar-powered water pumping for agriculture, especially in areas without grid access.