Chemistry of Buffalo Milk

Chemistry of Buffalo Milk

Buffalo milk is the second most produced milk globally (after cow milk) and is the foundation of iconic products like Italian Mozzarella di Bufala Campana (PDO), Indian paneer, and Middle Eastern cheeses.

1. Average Composition of Buffalo Milk (per 100 mL)

ComponentAmountEnergy
Water81–84 g
Total Solids16–19 g
Fat7.0–9.0 g (avg. 7.5–8.0 g)65–80 kcal
Protein4.0–5.0 g (avg. 4.5 g)16–20 kcal
Lactose4.5–5.2 g (avg. 4.8 g)18–21 kcal
Ash (minerals)0.8–0.9 g
Energy100–120 kcal


2. Chemical Components

A. Milk Fat (7.0–9.0 % — highest among major dairy species)

  • Largest fat globules (avg. 5–8 μm) → rapid creaming, excellent for butter & ghee
  • Very high saturated fatty acids (~70 %)
  • Lower medium-chain fatty acids than goat/sheep milk
  • Contains natural peroxides → higher oxidative stability than cow milk fat
  • Whiter color due to lack of β-carotene (converted to vitamin A)
Fatty AcidBuffalo (%)Cow (%)
C16:0 Palmitic30–3525–30
C18:0 Stearic12–1510–15
C18:1 Oleic25–3020–30
C4–C10 (short/medium)5–88–12


B. Proteins (4.0–5.0 %)

FeatureBuffalo MilkCow Milk
Total caseinHigher (3.5–4.2 g)2.6–3.0 g
β-caseinHigh A2 variantMixed A1/A2
Casein micelle sizeLarger (150–200 nm)100–150 nm
Whey proteinsLower proportionHigher

Result: Superior heat stability and rennet coagulation → ideal for mozzarella stretching (pasta filata).

C. Lactose & Carbohydrates

4.5–5.2 % — similar to cow/sheep milk, slightly higher than goat.

D. Minerals

MineralBuffalo (mg/100 mL)Cow (mg/100 mL)
Calcium160–200110–130
Phosphorus120–15090–100
Magnesium15–2010–12
Potassium100–130130–150


3. Comparison: Buffalo vs Cow vs Human

ParameterBuffaloCowHuman
Fat (g/100 mL)7.5–8.03.5–4.53.5–4.5
Protein (g/100 mL)4.53.51.0
Lactose (g/100 mL)4.84.87.0
Calcium (mg/100 mL)18012030
Fat globule size (μm)5–84–5~2
Total Solids (%)16–1912–1312–13
Energy (kcal/100 mL)100–12060–7065–70
Cheese yield (kg/100 L)20–259–12N/A

4. Unique Chemical Advantages

  • Highest fat content → richest mouthfeel, best for cream, butter, ghee
  • No β-carotene → pure white color (ideal for mozzarella)
  • Large fat globules → fast natural separation
  • High casein & calcium → superior curd firmness and stretchability
  • High peroxide value → longer shelf life of fat-rich products
  • Low water content → 1 liter buffalo milk = nutritional equivalent of ~1.5 liters cow milk

Summary

Buffalo milk is chemically the richest and most concentrated of all major dairy milks — with the highest fat, high protein, large fat globules, and pure white color. These properties make it technologically perfect for premium cheeses (especially mozzarella), traditional sweets (gulab jamun, rasgulla), and high-energy dairy products. Though produced in smaller volumes than cow milk, its superior composition commands premium prices worldwide.


Related Topics
Chemistry of Human Milk
Chemistry of Cow Milk
Chemistry of Goat Milk
Chemistry of Camel Milk
Chemistry of Sheep Milk
Chemistry of Donkey Milk

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