Bihar Board 12th Chemistry Answer Key 7.2.2025


Law of Radioactive Decay

Law of Radioactive Decay

Law of Radioactive Decay


Law of Radioactive Decay

According to law of radioactive decay, the rate of decay of a radioactive substance is directly proportional to the number of atoms present.
Hence, − dN/dt ∝ N
or, − dN/dt = λ N     ----- Equation-1
where, λ is proportionality constant called decay constant is characteristic of the emitter measure the rate of decay. The negative sign indicates that the number of radioactive nuclei decreases over the time.
or, λ = (− dN/dt) / N

Thus, we can say that the decay constant is the ratio of the number of atoms of a radioactive substance in unit time to the number of atoms present. It follows the first order kinetics and is expressed in per second (sec).
From equation-1, we have-
− dN/dt = λ N
or, dN/dt = − λN
on integrating this equation we get-
∫dN/dt = − ∫λ N
or, ln N = − λt + I     ----- Equation-2
where I is integrating constant.
When t = to then N = No,
Hence, ln No = I

Putting the value of I in equation-2, we get-
ln N = − λt + ln No
or, ln N − ln No = − λt
or, ln N/No = − λt
or, ln No/N = λt
or,
Law of Radioactive Decay
If t = t1/2 then, N = N/2
Putting the value of t and N in the above equation, we get-
Law of Radioactive Decay | Half Life of Law of Radioactive Decay
Hence, the half life of radioactive substance is inversely proportional to its decay constant.

A radio element has activity of 630 and 610 counts per minute at times t1 and t2 differing by one hour. What is its half life?

HINTS:
Radioactive decay follows first order kinetics, hence-
A radio element has activity of 630 and 610 counts per minute at times t1 and t2 differing by one hour. What is its half life?

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B.Sc. 2nd Semester Chemistry

Session: 2024-2028


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